Proton Conductivity of Graphene-based Nafion® Catalyst Layer for Polymer Electrolyte Membrane Fuel Cell
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An overview of organic/inorganic membranes based on sulfonated poly ether ether ketone for application in proton exchange membrane fuel cells
Nowadays, proton exchange membrane fuel cells (PEMFCs) are the most promising green energy conversion devices for portable and stationary applications. Traditionally, these devices were based onperfluoro-sulfonic acid electrolytes membranes, given the commercial name Nafion. Nafion is the mostused electrolyte membrane till now; because of its high electrochemical properties su...
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Sulfonated polyether ether ketone (SPEEK) is categorized in a nonfluorinated aromatic hydrocarbon proton exchange membrane (PEM) group and considered as a suitable substitute for common per-fluorinated membranes, such as Nafion, due to wider operating temperature, less feed gas crossover, and lower cost. Since modeling results in a better understanding of a phenomenon, in this study a dynamic o...
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Sulfonated poly (ether ether ketone) (SPEEK) with a low degree of sulfonation (DS = 40%) was prepared for proton exchange membrane fuel cells (PEMFC). Poly (ether ether ketone) (PEEK) was sulfonated in concentrated H2SO4 under N2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (H-NMR) technique. After preparation of the SPEEK polymer, the obtained polymer was dissolved i...
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The high methanol crossover and high cost of Nafion® membrane are the major challenges for direct methanol fuel cell application. With the aim of solving these problems, a non-Nafion polymer electrolyte membrane with low methanol permeability and high proton conductivity based on the sodium alginate (SA) polymer as the matrix and sulfonated graphene oxide (SGO) as an inorganic filler (0.02-0.2 ...
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Gas diffusion layers are essential components of proton exchange membrane fuel cell since the reactants should pass through these layers. Mass transport in these layers is highly dependent on porosity. Many of simulations have assumed, for simplicity, the porosity of GDL is constant, but in practice, there is a considerable variation in porosity along gas diffusion layers. In the present study ...
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